| Sunday 22 April 2007 |
| Dutch Holland Casino Eredivisie |
| FC Utrecht |
1 (0) |
PSV |
1 (1) |
| Wednesday 11 April 2007 |
| European Champion Clubs Cup Quarter Final 2nd Leg |
| Liverpool |
1 (0) |
PSV |
0 (0) |
| Saturday 7 April 2007 |
| Dutch Holland Casino Eredivisie |
| NEC |
2 (2) |
PSV |
1 (0) |
| Saturday 31 March 2007 |
| Dutch Holland Casino Eredivisie |
| NAC |
1 (0) |
PSV |
1 (0) |
| Sunday 11 March 2007 |
| Dutch Holland Casino Eredivisie |
| Excelsior |
0 (0) |
PSV |
0 (0) |
| Saturday 17 February 2007 |
| Dutch Holland Casino Eredivisie |
| Heracles |
0 (0) |
PSV |
2 (0) |
| Sunday 11 February 2007 |
| Dutch Holland Casino Eredivisie |
| Sparta |
1 (0) |
PSV |
1 (0) |
| Sunday 28 January 2007 |
| Dutch Holland Casino Eredivisie |
| Roda JC |
2 (1) |
PSV |
0 (0) |
| Tuesday 26 December 2006 |
| Dutch Holland Casino Eredivisie |
| Feyenoord |
1 (1) |
PSV |
1 (1) |
| Saturday 9 December 2006 |
| Dutch Holland Casino Eredivisie |
| FC Groningen |
0 (0) |
PSV |
2 (0) |
| Saturday 2 December 2006 |
| Dutch Holland Casino Eredivisie |
| Vitesse |
0 (0) |
PSV |
1 (1) |
| Wednesday 22 November 2006 |
| European Champion Clubs Cup Group C |
| Liverpool |
2 (0) |
PSV |
0 (0) |
| Sunday 12 November 2006 |
| Dutch Holland Casino Eredivisie |
| Ajax |
0 (0) |
PSV |
1 (0) |
| Saturday 28 October 2006 |
| Dutch Holland Casino Eredivisie |
| RKC |
0 (0) |
PSV |
3 (0) |
| Sunday 22 October 2006 |
| Dutch Holland Casino Eredivisie |
| AZ |
1 (0) |
PSV |
3 (3) |
| Wednesday 18 October 2006 |
| European Champion Clubs Cup Group C |
| Galatasaray |
1 (1) |
PSV |
2 (0) |
| Sunday 1 October 2006 |
| Dutch Holland Casino Eredivisie |
| Heerenveen |
0 (0) |
PSV |
0 (0) |
| Wednesday 27 September 2006 |
| European Champion Clubs Cup Group C |
| Bordeaux |
0 (0) |
PSV |
1 (0) |
| Saturday 23 September 2006 |
| Dutch Holland Casino Eredivisie |
| ADO Den Haag |
0 (0) |
PSV |
2 (0) |
| Saturday 9 September 2006 |
| Dutch Holland Casino Eredivisie |
| Willem II |
1 (1) |
PSV |
3 (3) |
| Sunday 27 August 2006 |
| Dutch Holland Casino Eredivisie |
| FC Twente |
1 (0) |
PSV |
0 (0) |
