| Saturday 13 May 2006 |
| Spanish Primera Liga |
| Villarreal |
2 (1) |
Racing Santander |
0 (0) |
| Sunday 7 May 2006 |
| Spanish Primera Liga |
| Real Madrid |
3 (1) |
Villarreal |
3 (2) |
| Wednesday 3 May 2006 |
| Spanish Primera Liga |
| Villarreal |
2 (2) |
Malaga |
1 (1) |
| Sunday 30 April 2006 |
| Spanish Primera Liga |
| Getafe |
1 (1) |
Villarreal |
1 (1) |
| Tuesday 25 April 2006 |
| European Champion Clubs Cup Semi Final 2nd Leg |
| Villarreal |
0 (0) |
Arsenal |
0 (0) |
| Saturday 22 April 2006 |
| Spanish Primera Liga |
| Villarreal |
0 (0) |
Real Sociedad |
2 (2) |
| Wednesday 19 April 2006 |
| European Champion Clubs Cup Semi Final 1st Leg |
| Arsenal |
1 (1) |
Villarreal |
0 (0) |
| Friday 14 April 2006 |
| Spanish Primera Liga |
| Barcelona |
1 (1) |
Villarreal |
0 (0) |
| Sunday 9 April 2006 |
| Spanish Primera Liga |
| Villarreal |
1 (0) |
Deportivo La Coruna |
1 (0) |
| Tuesday 4 April 2006 |
| European Champion Clubs Cup Quarter Final 2nd Leg |
| Villarreal |
1 (0) |
Inter Milan |
0 (0) |
| Saturday 1 April 2006 |
| Spanish Primera Liga |
| Real Zaragoza |
0 (0) |
Villarreal |
1 (1) |
| Wednesday 29 March 2006 |
| European Champion Clubs Cup Quarter Final 1st Leg |
| Inter Milan |
2 (1) |
Villarreal |
1 (1) |
| Saturday 25 March 2006 |
| Spanish Primera Liga |
| Villarreal |
1 (0) |
Real Betis |
2 (2) |
| Wednesday 22 March 2006 |
| Spanish Primera Liga |
| Valencia |
1 (1) |
Villarreal |
1 (0) |
| Saturday 18 March 2006 |
| Spanish Primera Liga |
| Villarreal |
1 (1) |
Atletico Madrid |
1 (0) |
| Sunday 12 March 2006 |
| Spanish Primera Liga |
| Mallorca |
1 (1) |
Villarreal |
1 (1) |
| Saturday 4 March 2006 |
| Spanish Primera Liga |
| Villarreal |
3 (1) |
CD Alaves |
2 (2) |
| Sunday 26 February 2006 |
| Spanish Primera Liga |
| Athletic Bilbao |
1 (1) |
Villarreal |
1 (1) |
| Saturday 18 February 2006 |
| Spanish Primera Liga |
| Villarreal |
4 (3) |
Espanyol |
0 (0) |
| Sunday 12 February 2006 |
| Spanish Primera Liga |
| Celta Vigo |
1 (1) |
Villarreal |
0 (0) |
| Sunday 5 February 2006 |
| Spanish Primera Liga |
| Villarreal |
1 (0) |
Cadiz |
1 (1) |
| Sunday 29 January 2006 |
| Spanish Primera Liga |
| Sevilla |
2 (1) |
Villarreal |
0 (0) |
| Sunday 22 January 2006 |
| Spanish Primera Liga |
| Villarreal |
2 (0) |
Osasuna |
1 (1) |
| Sunday 15 January 2006 |
| Spanish Primera Liga |
| Racing Santander |
1 (1) |
Villarreal |
0 (0) |
| Sunday 8 January 2006 |
| Spanish Primera Liga |
| Villarreal |
0 (0) |
Real Madrid |
0 (0) |
| Wednesday 21 December 2005 |
| Spanish Primera Liga |
| Malaga |
0 (0) |
Villarreal |
0 (0) |
| Sunday 18 December 2005 |
| Spanish Primera Liga |
| Villarreal |
2 (1) |
Getafe |
1 (1) |
| Saturday 10 December 2005 |
| Spanish Primera Liga |
| Real Sociedad |
1 (1) |
Villarreal |
3 (1) |
| Wednesday 7 December 2005 |
| European Champion Clubs Cup Group D |
| Villarreal |
1 (0) |
Lille |
0 (0) |
| Sunday 4 December 2005 |
| Spanish Primera Liga |
| Villarreal |
0 (0) |
Barcelona |
2 (1) |
| Sunday 27 November 2005 |
| Spanish Primera Liga |
| Deportivo La Coruna |
0 (0) |
Villarreal |
2 (0) |
| Tuesday 22 November 2005 |
| European Champion Clubs Cup Group D |
| Man Utd |
0 (0) |
Villarreal |
0 (0) |
| Saturday 19 November 2005 |
| Spanish Primera Liga |
| Villarreal |
0 (0) |
Real Zaragoza |
0 (0) |
| Saturday 5 November 2005 |
| Spanish Primera Liga |
| Villarreal |
1 (1) |
Valencia |
0 (0) |
| Wednesday 2 November 2005 |
| European Champion Clubs Cup Group D |
| Benfica |
0 (0) |
Villarreal |
1 (0) |
| Sunday 30 October 2005 |
| Spanish Primera Liga |
| Atletico Madrid |
1 (1) |
Villarreal |
1 (0) |
| Wednesday 26 October 2005 |
| Spanish Primera Liga |
| Real Betis |
2 (1) |
Villarreal |
3 (1) |
| Sunday 23 October 2005 |
| Spanish Primera Liga |
| Villarreal |
3 (3) |
Mallorca |
0 (0) |
| Tuesday 18 October 2005 |
| European Champion Clubs Cup Group D |
| Villarreal |
1 (0) |
Benfica |
1 (0) |
| Saturday 15 October 2005 |
| Spanish Primera Liga |
| CD Alaves |
1 (1) |
Villarreal |
1 (1) |
| Sunday 2 October 2005 |
| Spanish Primera Liga |
| Villarreal |
3 (1) |
Athletic Bilbao |
1 (1) |
| Tuesday 27 September 2005 |
| European Champion Clubs Cup Group D |
| Lille |
0 (0) |
Villarreal |
0 (0) |
| Saturday 24 September 2005 |
| Spanish Primera Liga |
| Espanyol |
1 (0) |
Villarreal |
2 (1) |
| Wednesday 21 September 2005 |
| Spanish Primera Liga |
| Villarreal |
1 (0) |
Celta Vigo |
2 (1) |
| Sunday 18 September 2005 |
| Spanish Primera Liga |
| Cadiz |
1 (1) |
Villarreal |
1 (1) |
| Wednesday 14 September 2005 |
| European Champion Clubs Cup Group D |
| Villarreal |
0 (0) |
Man Utd |
0 (0) |
| Sunday 11 September 2005 |
| Spanish Primera Liga |
| Villarreal |
1 (0) |
Sevilla |
1 (1) |
| Sunday 28 August 2005 |
| Spanish Primera Liga |
| Osasuna |
2 (1) |
Villarreal |
1 (0) |
| Wednesday 24 August 2005 |
| European Champion Clubs Cup Third Qualifying Round 2nd Leg |
| Villarreal |
2 (1) |
Everton |
1 (0) |
| Tuesday 9 August 2005 |
| European Champion Clubs Cup Third Qualifying Round 1st Leg |
| Everton |
1 (1) |
Villarreal |
2 (2) |
